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In the title compound, [Co(N 3 ) 2 (H 2 O) 4 ]·C 14 H 12 N 2 O 4 ·2H 2 O, the metal complex mol­ecule is centrosymmetric, the Co(II) ion being six-coordinated by two azide N atoms and four aqua O atoms with a  trans -octa­hedral geometry. The zwitterionic organic mol­ecule is also centrosymmetric. In the crystal, the components are associated into a two-dimensional network through O—H⋯O hydrogen bonds. Further O—H⋯O and O—H⋯N inter­actions give a three-dimensional structure. The free water molecule is disordered over two positions in a 0.787 (5):0.213 (5) ratio.

Tetraaquadiazidocobalt(II) 4,4′-dicarboxylato-1,1′-ethylenedipyridinium dihydrate