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In the structure of the title compound, C 8 H 12 NO + ·C 7 H 5 O 6 S − ·H 2 O, isolated from the reaction of 2-(4-amino­phen­yl)ethanol with 5-sulfosalicylic acid, the cations form head-to-tail hydrogen-bonded chains through  C   1   1 (9) anilinium N + —H⋯O hydrox­yl  inter­actions while the anions also form parallel but  C   1   1 (8)-linked chains through carboxylic acid O—H⋯O sulfonate  inter­actions. These chains inter-associate through a number of N + —H⋯O and O—H⋯O bridging inter­actions, giving a two-dimensional array in the  ab  plane.

4-(2-Hydroxyethyl)anilinium 3-carboxy-4-hydroxybenzenesulfonate monohydrate