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In the title complex, [Mn(C 19 H 12 BrN 3 O 2 )Cl(C 3 H 7 NO)], the Mn III  ion is coordinated by two N and two O atoms from the tetra­dentate Schiff base ligand, one O atom from the dimethyl­formamide ligand and a Cl anion in a distorted octa­hedral geometry. In the crystal structure, weak inter­molecular C—H⋯Cl hydrogen bonds link the mol­ecules into centrosymmetric dimers with a short distance of 3.878 (3) Å between the centroids of the aromatic rings.

{2,2′-[5-Bromopyridine-2,3-diylbis(nitrilomethylidyne)]diphenolato}chlorido(dimethylformamide)manganese(III)