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In the structure of the title compound, [Mo(C 11 H 13 NO 3 )O 2 (CH 3 OH)], the Mo VI  ion is octahedrally coordinated by two oxide O atoms, the N atom and two deprotonated OH groups of the tridentate Schiff base ligand 2-meth­oxy-6-[(2-oxidoprop­yl)imino­meth­yl]phenolate and by a methanol O atom. In the crystal structure, two complexes are linked  via  O—H⋯O hydrogen bonds, yielding a centrosymmetric arrangement involving the methanol hydr­oxy group and one of the ligand O atoms coordinated to the Mo VI  ion.

Methanol{2-methoxy-6-[(2-oxidopropyl)iminomethyl]phenolato}dioxidomolybdenum(VI)