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In the mol­ecular structure of the title compound, [Cr 2 Cl 4 (C 26 H 36 N 2 ) 2 (C 4 H 8 O)]·4.5CH 2 Cl 2 , the two Cr II  centers are bridged by three Cl atoms, forming a dinuclear complex. Each Cr II  center is coordinated by one chelating bis­(2,6-diisopropyl­phen­yl)ethane-1,2-diimine ligand  via  both N atoms. An additional chloride ion binds to one chromium center, whereas an additional tetra­hydro­furan mol­ecule coordinates to the second Cr II  center. The coordination geometry at each Cr II  center can be best described as distorted octa­hedral.

acta crystallographica. section e

Bis[N,N′-bis(2,6-diisopropylphenyl)ethane-1,2-diimine]-1κ2N,N′;2κ2N,N′-tri-μ-trichlorido-1:2κ6Cl:Cl-chlorido-1κCl-tetrahydrofuran-2κO-dichromium(II) dichloromethane 4.5-solvate