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In the title compound, [Ni(C 12 H 8 N 5 ) 2 (H 2 O) 4 ]·2H 2 O, the Ni II  atom is coordinated by the two N atoms [Ni—N = 2.094 (3) Å] and four O atoms [Ni—O = 2.063 (3)–2.083 (2) Å] in a distorted octa­hedral geometry. The mol­ecule is centrosymmetric and the Ni II  atom is located on an inversion center. Inter­molecular O—H⋯N and O—H⋯O hydrogen bonds link the complex into a three-dimensional supra­molecular framework.

Tetraaquabis[3-(3-pyridyl)-5-(4-pyridyl)-1,2,4-triazolido]nickel(II) dihydrate