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In the methanol solvate of the title 1:1 cocrystal, C 29 H 28 F 6 N 4 OS·C 5 H 9 NO 2 ·CH 4 O, the  l -proline mol­ecule exists as a zwitterion. In the crystal, the disubstituted thio­urea,  l -proline and methanol mol­ecules are linked by N—H⋯O and N—H⋯N hydrogen bonds, forming a two-dimensional array in the  ab  plane.

acta crystallographica. section e

1-[3,5-Bis(trifluoromethyl)phenyl]-3-[(5-ethenyl-1-azabicyclo[2.2.2]octan-2-yl)(6-methoxyquinolin-4-yl)methyl]thiourea–<scp>L</scp>-proline–methanol (1/1/1)

1-[3,5-Bis(trifluoromethyl)phenyl]-3-[(5-ethenyl-1-azabicyclo[2.2.2]octan-2-yl)(6-methoxyquinolin-4-yl)methyl]thiourea–L-proline–methanol (1/1/1)