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The three-dimensional coordination polymer, [Mn 2 (C 12 H 6 O 4 ) 2 (C 12 H 6 N 2 O 2 )(H 2 O)]  n  , features a water-coord­inated Mn II  ion and an N-heterocycle-chelated Mn II  ion, both in six-coordinate octa­hedral geometries. Of the two rigid dianions, one is bonded to four Mn II  ions, with each of the O atoms being connected to a different metal ion. The other dianion uses one carboxyl­ate group to chelate to one Mn II  ion and its other carboxyl­ate group to bind to two Mn II  ions.

Poly[aquabis(μ4-naphthalene-1,4-dicarboxylato)(1,10-phenanthroline-5,6-dione)dimanganese(II)]

Poly[aquabis(μ₄-naphthalene-1,4-dicarboxylato)(1,10-phenanthroline-5,6-dione)dimanganese(II)]