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In the title compound, [CuCl 3 (C 6 H 16 N 3 )]·H 2 O, the copper(II) ion is five-coordinated by two N atoms from the bidentate 4-(2-amino­ethyl)piperazin-1-ium cation and three chloride ions in a distorted square-pyramidal environment. Inter­molecular N—H⋯Cl and O—H⋯Cl hydrogen bonds build up an intricate three-dimensional network.

[4-(2-Aminoethyl)piperazin-1-ium]trichloridocopper(II) monohydrate