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The title compound, the product of an acid-catalysed Wagner–Meerwein skeletal rearrangement, crystallizes as an ethanol monosolvate, C 20 H 21 NO 8 ·C 2 H 6 O. The title mol­ecule comprises a fused tricyclic system containing two five-membered rings (cyclo­pentane and tetra­hydro­furan) in the usual envelope conformations and one six-membered ring (piperidinone) adopting a flattened twist–boat conformation.

Methyl 4,5-diacetoxy-1-oxo-2-phenylperhydro-4,6-epoxycyclopenta[c]pyridine-7-carboxylate ethanol solvate