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The title compound, (C 44 H 38 P 2 )[AuCl(C 6 F 5 )] 2 ·2CH 2 Cl 2 , crystallizes with a twofold rotation axis through the central benzene ring in the bis-phospho­nium dication. In the crystal, the dications and anions are ordered into columns running parallel to the  c  axis by contacts of the pro-ylidic CH 2  groups with the Cl atom of one and an  ortho -F atom of another anion. The space between the columns is occupied by CH 2 Cl 2  solvent mol­ecules.

(m-Phenylenedimethylene)bis(triphenylphosphonium) bis[chlorido(pentafluorophenyl)aurate(I)] dichloromethane disolvate