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The title compound, [Ti(C 10 H 15 )(C 20 H 26 Si)], was obtained from the reaction of [Ti{η 5 :η 1 -C 5 Me 4 (CH 2 )}(η 5 -C 5 Me 5 )] with the alkynylsilane PhC 2 SiMe 2 H. The complex crystallizes with two independent mol­ecules in the asymmetric unit, which differ in the conformation of the propenyl unit, resulting in their having opposite helicity. No inter­molecular inter­actions or inter­actions involving the Si—H bond are present. The observed geometrical parameters are unexceptional compared to known structures of the same type.

acta crystallographica. section e

[1-Dimethylsilyl-2-phenyl-3-(η5-tetramethylcyclopentadienyl)prop-1-en-1-yl-κC1](η5-pentamethylcyclopentadienyl)titanium(III)