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In the title salt, [Cu(NCS)(C(6)H(6)N(4))(2)]Cl, the Cu(II) atom adopts a five-coordinated square-pyramidal geometry consisting of an N atom from a thio-cyanate anion and four N atoms from two chealting biimidazole ligands. The thio-cyanate ligand occupies the axial position and is, like the Cu(II) centre, located on a mirror plane. The cation and anion are linked into a linear chain by N-H⋯S and N-H⋯Cl hydrogen bonds.

Bis(2,2′-bi-1H-imidazole-κ2N3,N3′)(thiocyanato-κN)copper(II) chloride

Bis(2,2′-bi-1H-imidazole-κ²N³,N^3′)(thiocyanato-κN)copper(II) chloride