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The title compound, [Ag(C 9 H 5 N 2 O 4 )(C 9 H 6 N 2 O 4 )]·H 2 O, contains one independent Ag atom, a neutral 1 H -benzimidazole-5,6-dicarboxylic acid (bdcH), its monodeprotonated form,  i.e.  5-carboxyl­ato-1 H -1,3-benzimidazole-6-carboxylic acid (bdc), and one solvent water mol­ecule, the latter being disordered over three sites with site occupancy factors of 0.375 (× 2) and 0.25. In addition, the H atom on one carboxylic acid residue is disordered, being connected to each of the O atoms 50% of the time. The Ag atom is in a virtually linear geometry defined by two N atoms derived from the bdc and bdcH ligands. The three-dimensional supra­molecular structure is stablized by extensive O—H⋯O and N—H⋯O hydrogen bonds. An intramolecular O—H⋯O hydrogen bond is also present.

(1H-1,3-Benzimidazole-5,6-dicarboxylic acid)(5-carboxylato-1H-1,3-benzimidazole-6-carboxylic acid)silver(I) monohydrate