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The title complex, [Co 2 (C 5 HF 6 O 2 ) 2 (C 5 H 7 O 2 ) 2 (H 2 O) 2 ], is centrosymmetric with a crystallographic inversion center in the middle of the mol­ecule. The octa­hedrally coordinated Co II  atoms are bridged by two chelating acetyl­acetonate (acac) ligands and two more electron-poor 1,1,1,5,5,5-hexa­fluoro­pentane-2,4-dionato (hfac) ligands are bonded terminally in a solely chelating manner. The coordinated water mol­ecules form inter­molecular O—H⋯O hydrogen bonds with electron-rich acac O atoms of neighboring mol­ecules, leading to strings of mol­ecules along the  a  axis.

Bis[μ-pentane-2,4-dionato(1−)]bis{aqua[1,1,1,5,5,5-hexafluoropentane-2,4-dionato(1−)]cobalt(II)}