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In the mol­ecular structure of the title compound, also named penciclovir monohydrate, C 10 H 15 N 5 O 3 ·H 2 O, the 4-hydr­oxy-3-hydroxy­methyl­but-1-yl group is connected to guanine through an N atom of the imidazole ring. Water mol­ecules stabilize the mol­ecular packing by forming O—H⋯O hydrogen bonds. A three-dimensional network is generated  via  inter­molecular N—H⋯N, N—H⋯O, O—H⋯N and O—H⋯O hydrogen bonding.

9-[4-Hydroxy-3-(hydroxymethyl)butyl]guanine monohydrate