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The title compound, [FeCl 3 (C 12 H 18 N 4 )]·0.5CH 3 OH, contains an Fe III  ion in a distorted octa­hedral coordination environment. The neutral  N , N ′, N ′′-tridentate ligand adopts a  fac  coordination mode, and chloride ligands lie  trans  to each of the three coordinated N atoms. In the crystal, the complexes form columns extending parallel to the approximate local threefold axes of the FeN 3 Cl 3  octa­hedra, and the columns are arranged so that the uncoordinated nitrile groups align in an anti­parallel manner and the pyridyl rings form offset face-to-face arrangements [inter­planar separations = 2.95 (1) and 3.11 (1) Å; centroid–centroid distances = 5.31 (1) and 4.92 (1) Å]. The methanol solvent mol­ecule is disordered about a twofold rotation axis.

Trichlorido[(methyl{2-[methyl(2-pyridylmethyl)amino]ethyl}amino)acetonitrile]iron(III) methanol hemisolvate