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The structure of the title compound, [Ru(C 10 H 15 )(C 13 H 10 O)](C 24 H 20 B), consists of discrete [Cp*Ru(II)benzophenone] cations and tetra­phenyl­borate anions (Cp* = penta­methyl­cyclo­penta­dien­yl). Tethering the Cp*Ru group to one aryl ring of benzophenone results in average values of 1.42 (1) and 1.38 (1) Å for the C—C bond lengths in the Ru-tethered and untethered phenyl rings, respectively. The dihedral angle between the benzene and phenyl rings of the benzophenone group is 50.5 (1)°.

(η6-Benzophenone)(η5-pentamethylcyclopentadienyl)ruthenium(II) tetraphenylborate

(η⁶-Benzophenone)(η⁵-pentamethylcyclopentadienyl)ruthenium(II) tetraphenylborate