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In the title complex mol­ecule, [CdBr 2 (C 10 H 8 N 2 ) 2 ], the Cd II  ion is six-coordinated by two  cis -arranged bromide anions and four N atoms of two bidentate 2,2′-bipyridine ligands in a distorted octa­hedral geometry. The dihedral angle formed by the mean planes through the bipyridine ligands is 87.01 (11)°. In the crystal packing, π–π stacking inter­actions [centroid–centroid distances = 3.837 (6) and 3.867 (11) Å] link adjacent complex mol­ecules into chains running parallel to the  b  axis. The chains are further connected by inter­molecular C—H⋯Br hydrogen bonds into a three-dimensional network.

Bis(2,2′-bipyridine-κ2N,N′)dibromidocadmium(II)

Bis(2,2′-bipyridine-κ²N,N′)dibromidocadmium(II)