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The title compound, [Pt(C 15 H 18 NO 2 S)Cl], was obtained by the cyclo­metallation reaction of  cis -bis­(benzonitrile)dichlorido­platinum(II) with  N -benzyl­idene- l -methio­nine allyl ester in refluxing toluene. The Pt II  atom has a square-planar geometry and is tetra-coordinated by the Cl atom and the C, N and S atoms from the benzyl­idene methio­nine ester ligand. In the crystal structure, the S atoms show opposite chiral configurations with respect to the α-carbon of the methio­nine, reducing steric repulsion between the methyl and allyl ester groups.

acta crystallographica. section e

Racemic (RSC,SRS)-(2-{[1-allyloxycarbonyl-3-(methylsulfanyl)propyl]iminomethyl}phenyl-κ3S,N,C1)chloridoplatinum(II)