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In the crystal structure of the title compound, [Zn(C 6 H 5 COO) 2 (C 12 H 12 N 2 )]·C 6 H 5 COOH, the Zn atom is penta­coordinated in distorted square-pyramidal geometry by two O atoms of a benzoate anion and two N atoms of a 6,6′-dimethyl-2,2′-bipyridine ligand occupying the basal plane and an O atom of another benzoate anion located at the apical site. In the crystal structure, inter­molecular O—H⋯O and C—H⋯O hydrogen bonds and C—H⋯π inter­actions are present.

Dibenzoato-κO;κ2O,O′-(6,6′-dimethyl-2,2′-bipyridine-κ2N,N′)zinc(II)–benzoic acid (1/1)

Dibenzoato-κO;κ²O,O′-(6,6′-dimethyl-2,2′-bipyridine-κ²N,N′)zinc(II)–benzoic acid (1/1)