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The title compound, K 2 Sm(MoO 4 )(PO 4 ), has been prepared under atmospheric conditions using a high temperature solution growth (HTSG) method. The structure of K 2 Sm(MoO 4 )(PO 4 ) is isotypic with other  A2M (MoO 4 )(PO 4 ) compounds, where  A  = Na or K, and  M  = trivalent rare earth cation. It can be described as being built up from two-dimensional anionic layers with composition [Sm(MoO 4 )(PO 4 )] 2−  that are stacked along the  c  axis and are inter­connected by K +  cations which are in an eightfold coordination by O atoms. The SmO 8 , MoO 4  and PO 4  polyhedra exhibit 2 symmetry.

Dipotassium samarium(III) molybdate(VI) phosphate(V), K2Sm(MoO4)(PO4)

Dipotassium samarium(III) molybdate(VI) phosphate(V), K₂Sm(MoO₄)(PO₄)