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Dimeric mol­ecules of the title compound, [Ru 2 Cl 4 (C 12 H 18 ) 2 ], are located on a crystallographic centre of inversion with one mol­ecule in the asymmetric unit. The hexa­methyl­benzene rings are in an η 6 -coordination to the ruthenium centres, which are bridged by two chloride ligands. In addition, the ruthenium centres are bonded to another chloride ligand. The aromatic rings and the Ru 2 Cl 2  four-membered ring enclose a dihedral angle of 55.85 (6)°.

Di-μ2-chlorido-bis[chlorido(η6-hexamethylbenzene)ruthenium(II)]

Di-μ₂-chlorido-bis[chlorido(η⁶-hexamethylbenzene)ruthenium(II)]