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The title dinuclear copper(I) complex, {[Cu 2 (C 2 H 3 N)(C 12 H 10 N 2 )(C 25 H 22 P 2 ) 2 ](BF 4 ) 2 }  n  , contains 1,2-di-4-pyridyl­ethene, bis­(diphenyl­phosphino)methane and acetonitrile ligands. The two Cu atoms, one with an N 2 P 2  ligand set and the other with an NP 2  ligand set, are bridged by two bis­(diphenyl­phosphino)methane ligands, forming an eight-membered ring.

acta crystallographica. section e

catena-Poly[[[acetonitrilecopper(I)]-bis[μ-bis(diphenylphosphino)methane-κ2P:P′]-copper(I)-μ-1,2-di-4-pyridylethene] bis(tetrafluoridoborate)]