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In the crystal structure of the title compound, [Co(H 2 O) 6 ][Cu(C 12 H 11 N 2 O 5 )] 2 ·6H 2 O, the Co II  atom is located on an inversion center and coordinated by six water mol­ecules in a slightly distorted octa­hedral geometry. The Cu II  atom is chelated by the Schiff base ligand in a distorted CuN 2 O 2  square-planar geometry. An extensive O—H⋯O hydrogen-bonding network is present in the crystal structure.

Hexaaquacobalt(II) bis{[N-(4-methoxy-2-oxidobenzylidene)glycylglycinato]copper(II)} hexahydrate