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In the title compound, [CdCu 2 (C 12 H 11 N 2 O 5 ) 2 (H 2 O) 3 ]·2H 2 O, the Cu II  atoms are in a square plane of N 2 O 2  atoms contributed by the tetra­dentate Schiff base trianion. The Cu II  atoms are coordinated by one phenolate O atom, one imine N atom, one amido N atom and one carboxyl­ate O atom. The Cd II  atom is connected  via  the carboxyl­ate groups, forming a heterotrinuclear Cu II –Cd II –Cu II  system. The Cd II  atom is seven-coordinate in a penta­gonal-bipyramidal geometry with four O atoms from two carboxyl­ate groups and three aqua ligands. The heterotrinuclear mol­ecules are linked to the uncoordinated water mol­ecules by O—H⋯O hydrogen bonds into a three-dimensional framework.

Triaquabis{μ-N-[N-(4-methoxy-2-oxidobenzylidene)glycyl]glycinato(3−)}cadmium(II)dicopper(II) dihydrate