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The title complex, [Na(C 12 H 24 O 6 )] 2 [InNa(NCS) 6 (C 12 H 24 O 6 )]·1.5C 2 H 4 Cl 2 , has been synthesized by the reaction of 18-crown-6 with InCl 3  and NaSCN. The In atom has a six-coordinate octa­hedral environment, being bonded to the N atoms of six thio­cyanate groups. The bond lengths and angles show normal values. The crystal packing exhibits no significantly short inter­molecular contacts.

acta crystallographica. section e

Bis[(18-crown-6-κ6O)sodium] (18-crown-6-1κ6O)-μ-thiocyanato-1:2κ2S:N-pentathiocyanato-2κ5N-indate(III)sodium 1,2-dichloroethane sesquisolvate