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The title mononuclear nickel(II) complex, [Ni(C 18 H 18 N 2 O 4 )(H 2 O)], possesses crystallographic mirror symmetry. The Ni atom is five-coordinated in a square-pyramidal geometry, with two imine N and two phenolate O atoms of the Schiff base ligand in the square plane, and the water O atom in the axial position. In the crystal, the mol­ecules are linked  via  inter­molecular O—H⋯O hydrogen bonds, forming chains along the  a  axis.

Aqua{5,5′-dimethoxy-2,2-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}nickel(II)