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The title compound, [Sn 4 (C 4 H 9 ) 8 (C 15 H 12 NO 3 ) 2 (CH 3 O) 2 O 2 ], is a centrosymmetric dimer and displays a ladder type structural motif. There are four Sn IV  centres which can be divided into two sorts,  viz . two endocyclic and two exocyclic. The endo- and exocyclic Sn IV  centres are linked by bidentate deprotonated methanol and μ 3 -O atoms. Each exocyclic Sn IV  centre is also coordinated by a monodentate 2-[4-(2-hydroxy­benzyl­idene­amino)phen­yl]acetate ligand. Parts of the butyl groups were found to be disordered over two sets of sites.

Octabutylbis{(E)-2-[4-(2-hydroxybenzylideneamino)phenyl]acetato}di-μ2-methoxo-di-μ3-oxido-tetratin(IV)

Octabutylbis{(E)-2-[4-(2-hydroxybenzylideneamino)phenyl]acetato}di-μ₂-methoxo-di-μ₃-oxido-tetratin(IV)