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In the title complex, [Cd(C 14 H 9 N 5 ) 2 ](ClO 4 ) 2 , the Cd II  ion is coordinated by two tridentate 2-(1 H -1,2,4-triazol-1-yl)-1,10-phenanthroline ligands in a distorted octa­hedral CdN 6  environment. In both 2-(1 H -1,2,4-triazol-1-yl)-1,10-phenanthroline ligands, the 1,2,4-triazolyl ring and the 1,10-phenanthroline ring system are essentially coplanar [maximun deviations of 0.136 (7) and 0.273 (5) Å, respectively]. The dihedral angle between the mean planes of the ligands is 89.65 (4)°. In the crystal structure, there is a weak π–π stacking inter­action between a pyridine ring and a symmetry-related benzene ring with a centroid–centroid distance of 3.772 (3) Å.

Bis[2-(1H-1,2,4-triazol-1-yl-κN2)-1,10-phenanthroline-κ2N,N′]cadmium(II) bis(perchlorate)

Bis[2-(1H-1,2,4-triazol-1-yl-κN²)-1,10-phenanthroline-κ²N,N′]cadmium(II) bis(perchlorate)