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The title compound, C 2 H 8 N + ·C 10 H 11 N 2 O 5− , is a highly toxic herbicide known as dinoseb. The  sec -butyl group is disordered [occupancy ratio 0.828 (3):0.172 (3)], while the nitro group in the 6 position is twisted by 25° with respect to the ring plane. Pairs of –O − ⋯H—N + —H⋯ − O– bridges between phenolic O atoms generate eight-membered hydrogen-bonded rings.

(RS)-Dimethylammonium 2-sec-butyl-4,6-dinitrophenolate