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In the title compound, C 13 H 15 NO 3 S, the sole classical hydrogen-bond donor is involved in an intra­molecular O—H⋯N hydrogen bond. In the crystal structure, pairs of mol­ecules related by inversion centres are linked by pairs of weak inter­molecular C—H⋯O inter­actions; these centrosymmetric pairs are, in turn, linked further by weak inter­molecular C—H⋯O inter­actions, forming two-dimensional sheets oriented parallel to (101).

10-Ethynyl-2,3,6,6a,9,10-hexahydro-1H-6,9-methanopyrrolo[2,1-i][2,1]benzothiazol-10-ol 5,5-dioxide