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The title compound, penta­iron tripraseodymium dodeca­oxide (PrIG), has an iron garnet structure. There are two Fe site symmetries. One of the Fe atoms is coordinated by six O atoms, forming a slightly distorted octa­hedron, and hassite symmetry. The other Fe atom is coordinated by four O atoms, forming a slightly distorted tetra­hedron, and hassite symmetry. FeO 6  octa­hedra and FeO 4  tetra­hedra are linked together by corners. The Pr atom is coordinated by eight O atoms, forming a distorted dodeca­hedron, and has 222 site symmetry. The O atoms occupy the general positions.

Tripraseodymium pentairon(III) dodecaoxide, Pr3Fe5O12: a synchrotron radiation study

Tripraseodymium pentairon(III) dodecaoxide, Pr₃Fe₅O₁₂: a synchrotron radiation study