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The title compound, [Ni(C 9 H 45 N 2 O 4 ) 2 (H 2 O) 4 ]·2C 3 H 7 NO·2H 2 O, has the Ni II  center coordinated by four water mol­ecules and two N atoms from two 1 H -benzimidazole-5,6-dicarboxyl­ate ligands in an octa­hedral geometry. The mol­ecule inter­acts with the solvent water and dimethyl­formamide mol­ecules through N—H⋯O and O—H⋯O hydrogen bonds to form a three-dimensional supra­molecular network. The metal atom lies on a center of inversion.

Tetraaquabis(6-carboxy-1H-benzimidazole-5-carboxylato-κN3)nickel(II) dimethylformamide disolvate dihydrate

Tetraaquabis(6-carboxy-1H-benzimidazole-5-carboxylato-κN³)nickel(II) dimethylformamide disolvate dihydrate