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In the crystal structure of the title compound, [Ir(C 5 H 7 O 2 ) 3 (H 2 O)], the Ir III  atom is six-coordinated and situated in a slightly distorted octa­hedral environment. The complex contains both Ir—O and Ir—C bonds and was isolated from a reaction mixture of IrCl 3 (H 2 O)  x  , pentane-2,5-dione and NaHCO 3 . O—H⋯O hydrogen bonding between the water molecules and the carbonyl O atoms of adjacent molecules leads to a layered motif extending parallel to (010).

Bis(acetylacetonato-κ2O,O′)aqua(diacetylmethanido-κC)iridium(III)

Bis(acetylacetonato-κ²O,O′)aqua(diacetylmethanido-κC)iridium(III)