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The title compound, Nd 3 Fe 5 O 12  (NdIG), has an iron garnet structure. One of the Fe atoms is coordinated by six O atoms in a slightly distorted octa­hedral geometry and hassite symmetry. The other Fe atom is coordinated by four O atoms in a slightly distorted tetra­hedral geometry and hassite symmetry. The FeO 6  octa­hedron and FeO 4  tetra­hedron are linked together by corners. The Nd atom is coordinated by eight O atoms in a distorted dodeca­hedral geometry and has 222 site symmetry. The O atoms occupy general positions.

Trineodymium(III) pentairon(III) dodecaoxide, Nd3Fe5O12

Trineodymium(III) pentairon(III) dodecaoxide, Nd₃Fe₅O₁₂