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The title compound, C 5 H 4 Br 2 S 4 , consists of a statistically planar, 4-bromo-1,3-dithiole-2-thione unit [maximum deviation from the ring plane 0.001 (2) Å], with a bromo­ethyl­sulfanyl substituent in the 5-position. In the crystal structure, weak inter­molecular S⋯S [3.438 (15) and 3.522 (15) Å] and S⋯Br [3.422 (14) and 3.498 (14) Å] inter­actions generate a three-dimensional supra­molecular architecture.

4-Bromo-5-[(2-bromoethyl)sulfanyl]-1,3-dithiole-2-thione