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In the title two-dimensional coordination polymer, [Cd(NCS) 2 (C 6 H 5 N 5 ) 2 ]  n  , the Cd II  ion (site symmetry) is coordinated by two N atoms from two 2-(1 H -1,2,3-triazol-1-yl)pyrazine ligands and two N and two S atoms from four thio­cyanate anions. The N—Cd bond lengths range from 2.323 (2) to 2.3655 (19) Å and the S—Cd bond length is 2.7117 (7) Å. The associated  cisoid  angles vary from 84.99 (7) to 95.01 (7)°, indicating that the Cd II  ion assumes a distorted octa­hedral geometry. In the complex, each thio­cyanate anion functions as a bridging ligand, linking adjacent Cd II  ions with a separation of 6.4919 (6) Å, resulting in the formation of a two-dimensional sheet structure in the  bc  plane.

acta crystallographica. section e

Poly[di-μ-thiocyanato-κ2N:S;κ2S:N-bis[2-(1H-1,2,3-triazol-1-yl-κN3)pyrazine]cadmium(II)]