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The main mol­ecule of the title compound, C 45 H 30 N 6 ·CH 3 OH, has a non-planar core: the dihedral angles between the benzimidazole rings and the central benzene ring are 20.19 (10), 34.57 (8), and 44.59 (8)°, while the dihedral angles between the peripheral phenyl rings and the attached benzimidazole rings are 84.57 (7), 62.71 (6) and 51.73 (6)°. The tri-substituted benzene mol­ecule is connected to the methanol solvent mol­ecule through an O—H⋯N hydrogen bond, forming a 1:1 solvate. In the crystal structure, no significant π–π inter­actions are present, and the mol­ecules are associated through weak C—H⋯N and C—H⋯O(methanol) contacts.

1,3,5-Tris(N-phenylbenzimidazol-2-yl)benzene methanol solvate