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The title compound, [Ru(C 10 H 8 N 2 ) 2 (C 13 H 7 N 3 S)](PF 6 ) 2 ·CH 3 CN, was synthesized by the reaction of thio­phosgene and bis­(2,2′-bipyridine)(1,10-phenanthrolin-5-amine)ruthenium(II) bis­(hexa­fluoridophosphate). The Ru II  atom adopts a slightly distorted octa­hedral RuN 6  coordinaton formed by four N atoms of two bipyridine ligands and by two N atoms of the 1,10-phenantroline ligand. The isothio­cyanate group is almost linear, with an N—C—S angle of 174.4 (6)°. Two of the three hexa­fluoridophosphate counter-anions are located on inversion centres.

Bis(2,2′-bipyridine)(5-isothiocyanato-1,10-phenanthroline)ruthenium(II) bis(hexafluoridophosphate) acetonitrile solvate