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In the crystal of the title compound, C 18 H 22 N 2 O 4 S·2H 2 O, mol­ecules are linked into a one-dimensional chain structure by C—H⋯O, N—H⋯O, O—H⋯O and O—H⋯N hydrogen bonds.

4-(4-Diethylamino-2-hydroxybenzylideneammonio)-3-methylbenzenesulfonate dihydrate