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In the title compound, [Mn(C 11 H 8 N 3 O 2 S) 2 (H 2 O) 4 ]·2H 2 O, the Mn II  ion lies on an inversion centre and is coordinated by four water mol­ecules in equatorial positions and two N atoms from two 2-[4-(3-pyrid­yl)pyrimidin-2-ylsulfan­yl]acetate ligands in the axial positions. The water mol­ecules, including the uncoordinated water mol­ecules, and the acetate O atoms are involved in O—H⋯O and O—H⋯N hydrogen-bonding inter­actions, which link the components into layers parallel to the  a  ( b  +  c ) plane.

Tetraaquabis{2-[4-(3-pyridyl)pyrimidin-2-ylsulfanyl]acetato}manganese(II) dihydrate