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The title complex, [V 2 (C 8 H 7 O 3 ) 2 O 4 (C 12 H 8 N 2 ) 2 ], is a centrosymmetric dimer formed by two V V  complex units bridged by two μ 2 -oxido groups. The V V  atom is six-coordinated by three oxide O atoms, one O atom from a vanillinate ligand and two N atoms from a 1,10-phenanthroline ligand in a significantly distorted octa­hedral geometry. In the crystal structure, weak inter­molecular C—H⋯O hydrogen bonds connect the mol­ecules into a three-dimensional network.

Di-μ-oxido-bis[(4-formyl-2-methoxyphenolato-κO1)oxido(1,10-phenanthroline-κ2N,N′)vanadium(V)]

Di-μ-oxido-bis[(4-formyl-2-methoxyphenolato-κO¹)oxido(1,10-phenanthroline-κ²N,N′)vanadium(V)]