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In the title compound, [Co(C(4)H(3)N(2)S)(C(6)H(18)N(4))](Cl)PF(6), the Co(III) ion is coordinated by a tripod-like tetra-dentate ligand and a monoanionic N,S-bidentate ligand in an approximately octa-hedral CoN(4)OS geometry. The anionic S atom of the pyrimidine-2-thiol-ate (pymt) ligand is coordinated in the trans position to the primary amine N atom (Nprim) of the tris-(2-amino-ethyl)amine (tren) ligand. The crystal structure exhibits short inter-molecular N-H⋯N hydrogen bonds (N⋯N &lt;3.2 Å), and inter-molecular N-H⋯Cl and C-H⋯F contacts, leading to the formation of an infinite two-dimensional network.

acta crystallographica. section e

trans-(Pyrimidine-2-thiolato-κ2N,S)[tris(2-aminoethyl)amine-κ4N,N′,N′′,N′′′]cobalt(III) chloride hexafluoridophosphate