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The title compound, {(C(2)H(8)N)(2)[Zn(2)(C(8)H(4)O(4))(3)(C(2)H(7)N)(2)]·2C(3)H(7)NO·6H(2)O}(n), consists of two-dimensional non-inter-penetrated sheets with 6(3) topology, which are stacked together in an …ABAB… packing mode along the c axis. The distance between adjacent A and B sheets is ca 7.3 Å. In the structure, the Zn(II) center is coordinated by three O atoms from three terephthalate groups and one N atom from one dimethyl-amine ligand, adopting a distorted tetra-hedral geometry. All solvent water mol-ecules are disordered. In the structure, N-H⋯O and O-H⋯O hydrogen bonds are observed.

acta crystallographica. section e

Poly[bis(dimethylammonium) [bis(dimethylamine-κN)tris(μ2-terephthalato-κ2O1:O4)dizinc(II)]N,N-dimethylformamide disolvate hexahydrate]