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In the title compound, [Mg(C 12 H 8 N 2 ) 2 (H 2 O) 2 ][Cr 2 O 7 ]·2C 12 H 8 N 2 , the cation and anion are situated on a twofold rotation axis. The Mg II  ion is coordinated by four N atoms from two 1,10-phenanthroline ligands and two O atoms from coordinated water mol­ecules in a distorted octa­hedral geometry. Inter­molecular O—H⋯N and O—H⋯O hydrogen bonds and π–π inter­actions between the aromatic rings [shortest centroid–centroid separation = 3.527 (2) Å] link the cations, anions and 1,10-phenanthroline solvent mol­ecules into a hydrogen-bonded cluster.

Diaquabis(1,10-phenanthroline)magnesium dichromate(VI) 1,10-phenanthroline disolvate