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In the title compound, [Fe 2 Zn(C 5 H 5 ) 2 (C 8 H 9 N 3 S) 2 ]·CH 3 OH, the dihedral angles between the substituted and unsubstituted cyclo­penta­dienyl rings are 89.34 (8) and 85.73 (9)°, respectively. The two Zn/S/C/N/N five-membered rings adopt envelope conformations, with the Zn II  atom at the flap. Each methanol solvent mol­ecule is linked to three ferrocene groups  via  inter­molecular O—H⋯N, N—H⋯O and C—H⋯O hydrogen bonds. The crystal structure is further consolidated by C—H⋯π inter­actions.

Bis(ferrocenecarbaldehyde 4-methylthiosemicarbazonato-κ2N1,S)zinc(II) methanol solvate

Bis(ferrocenecarbaldehyde 4-methylthiosemicarbazonato-κ²N¹,S)zinc(II) methanol solvate