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In the title compound, [Ag(C 14 H 10 N 4 O) 2 ]CF 3 CO 2 , the Ag I  ion is coordinated by two N atoms of the pyridine rings of two  N ′-(3-cyano­benzyl­idene)isonicotinohydrazide ligands in a nearly linear geometry. In the crystal structure, a combination of close contacts formed  via  Ag⋯N inter­actions [Ag⋯N = 3.098 (2) and 3.261 (2) Å] from symmetry-related mol­ecules and inter­molecular N—H⋯O hydrogen bonds between CF 3 CO 2−  anions and the hydrazone groups of two ligands give rise to chains. Furthermore, there are Ag⋯O inter­actions with a separation of 2.765 (2) Å between chains. The F atoms of the CF 3 CO 2−  anion are disordered over two sites with refined occupancies of 0.593 (5) and 0.407 (5).

Bis[N′-(3-cyanobenzylidene)isonicotinohydrazide]silver(I) trifluoroacetate