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In the title compound, [Ni(C 12 H 8 N 2 )(H 2 O) 4 ](C 12 H 10 O 8 ), the Ni II  ion is six-coordinated by two N atoms from one phenanthroline ligand and by the O atoms of four water mol­ecules in a distorted octa­hedral geometry. In the crystal, inter­molecular O—H⋯O hydrogen bonds form an extensive three-dimensional network, which consolidates the crystal packing.

Tetraaqua(1,10-phenanthroline)nickel(II) 3,6-dicarboxybicyclo[2.2.2]oct-7-ene-2,5-dicarboxylate