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The Zn II  atom in the title compound, [Zn(C 14 H 11 N 3 O 2 S)(C 12 H 8 N 2 )]·0.5C 10 H 8 N 2 , is  N , N ′-chelated by the  N -heterocycle and  N , O , S -chelated by the deprotonated Schiff base in a square-pyramidal environment. The hydr­oxy group of the Schiff base is a hydrogen-bond donor to 4,4′-bipyridine, which is located about a center of inversion, resulting in the formation of a supra­molecular trimeric unit.

acta crystallographica. section e

[1-(4-Hydroxy-2-oxidobenzylidene)-4-phenylthiosemicarbazonato-κ3N,O,S](1,10-phenanthroline-κ2N,N′)zinc(II)–4,4′-bipyridine (2/1)